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Category: Miscellaneous Reagents /// Appearance: Clear Colourless Oil /// Application Notes: Diiodomethane is a compound widely used as a reagent for cyclopropanation in the Simmons-Smith reaction with a Zn-Cu couple. Diiodomethane also undergoes photolysis, and, if in the presence of olefins, will yield cyclopropanes with high stereospecificity. /// References: Maier, G., et al.: J. Am. Chem. Soc., 112, 5117 (1990)| Philip D., et al.: J. Am. Chem. Soc., 123, 4197 (2001)| Zheng, X., et al.: J. Phys. Chem. A, 104, 6880 (2000)